This site will look much better in a browser that supports web standards, but it is accessible to any browser or Internet device.

Skip Navigationskip menu and banner
University of Wyoming

Publications

J. J. Adams,  A. Lau, N. Arulsamy, and  D. M. Roddick, “Synthesis and Platinum Coordination Chemistry of the Perfluoroalkyl Acceptor Pincer Ligand, 1,3-(CH2P(CF3)2)2C6H4”  Inorg. Chem. 2007, 46, 11328-11334

Jeffrey L. Butikofer, Thomas G. Parson, and Dean M. Roddick, "Adduct Studies and Reactivity of trans-[(C2F5)2MeP]2Pt(Me)X (X = O2CCF3, OTf, OSO2F)", Organometallics, 2006, 25, 6108-6114.

Jason D. Palcic, P. N. Kapoor, Dean M. Roddick, and R. Gregory Peters, “Perluofroalkylphosphine Coordination Chemistry of Platinum: Synthesis of (C2F5)2PPh and (C2F5)PPh2 Complexes of Platinum(II),” J. Chem. Soc., Dalton Trans., 2004, 1644-1647.

R. K. Merwin, A. C. Ontko, J. F. Houlis, and D. M. Roddick, D. M., “Synthesis and Characterization of CpMn(dfepe)(L) Complexes (dfepe = (C2F5)2PCH2CH2P(C2F5)2; L = CO, H2, N2). An Unusual Example of a Dihydride to Dihydrogen Photochemical Conversion,” Polyhedron 2004, 23, 2873-2878.

J. L. Butikofer, E. W. Kalberer, W. C. Schuster, and D. M. Roddick, “The Crystal Structure of Dichloro(norbornadiene)platinum(II): A Comparison to Dichloro(cyclooctadiene)platinum(II),”  Acta Cryst. C. 2004, m353-m354.

E. W. Kalberer and D. M. Roddick, “Carbon Hybridization Effects on Platinum-Carbon Bond Protonolysis: Synthesis and Protonation Chemistry of (dfepe)Pt(η2-alkyne) Complexes,” Organometallics, 2004, 23, 4209-4212.

E. W. Kalberer, J. F. Houlis, and D. M. Roddick, “Protolytic Stability of (dfepe)Pt(Ph)O2CCF3: Supporting Evidence for a Concerted SE2 Protonolysis Mechanism”, Organometallics, 2004, 23, 4112-4115.

J. D. Palcic, P. N. Kapoor, D. M. Roddick, and R. G. Peters, “Perfluoroalkylphosphine Coordination Chemistry of Platinum: Synthesis of (C2F5)2PPh and (C2F5)PPh2 Complexes of Platinum(II),” J. C. S., Dalton Trans. 2004, 1644-1647.

J. L. Butikofer, J. M. Hoerter, R. G. Peters, and D. M. Roddick, “Synthesis and Reactivity of [(C2F5)2MeP]2Pt(Me)X (X = Me, O2CCF3, OTf, OSO2F): A Reactivity Comparison with Chelate Acceptor Analogues,” Organometallics, 2004, 23, 400-408.

B. L. Bennett, S. White, B. Hodges, D. Rodgers, A. Lau, and D. M. Roddick, “(Fluoroalkyl)phosphine Complexes of Nickel(0) and Cobalt(I)”, J. Organometal. Chem. 2003, 679, 65-71.

S. White, E. W. Kalberer, B. L. Bennett, and D. M. Roddick, “Synthesis, Structure, and Characterization of a Bridging Ethylidene (Perfluoroalkyl)phosphine Platinum Complex”, Organometallics, 2001, 20, 5731.

B. L. Bennett, J. M. Hoerter, J. F. Houlis, and D. M. Roddick, “Metal-Alkyl Bond Protonolysis Studies of (dfepe)Pt(Me)X Complexes in Acidic Media," Organometallics, 2000, 19, 615.

J. M. Hoerter, R.C. Schnabel, and D. M. Roddick, “The Fate of a Bimetallic Ethylene Dimerization Catalyst: Synthesis and Structure of (dfepe)2Ir2(H)(µ-H)(µ-η1,η3-C4H6),” Organometallics 1999, 18, 5717-5720.

S. White, B. L. Bennett, and D. M. Roddick, “Organometallics in Acidic Media: Catalytic Dimerization of Ethylene by (Perfluoroalkyl)phosphine Complexes of Platinum and Palladium in Trifluoroacetic Acid,” Organometallics 1999, 18, 2536.

J. F. Houlis and Dean M. Roddick, "Organometallics in Superacidic Media: Generation of Highly Electrophilic (Fluoroalkyl)phosphine Pt(II) Cationic Complexes," J. Am. Chem. Soc. 1998, 120, 11020.

Allyn C. Ontko, James F. Houlis, R. Chris Schnabel, Dean M. Roddick, Tina P. Fong, Alan J. Lough, and Robert H. Morris, “Protonation and H2 Heterolysis Reactions of Electrophilic (η5-C5R5)Ru(dfepe)(X) (R = H, Me; X = H, OTf) Complexes”, Organometallics, 1998, 17, 5467.

R. G. Peters, S. White, and D. M. Roddick, "Activation of Aromatic C-H Bonds by (dmpe)Pt(Me)X (X = O2CCF3, OTf) Systems," Organometallic, 1998, 17, 4493.

R. Gregory Peters, Byron L. Bennett, R. Chris Schnabel, and Dean M. Roddick, “(Fluoroalkyl)phosphine Coordination Chemistry: Synthesis and Structure of {[µ,η1,η6-(C6H5)P(C2F5)2]Cr(CO)2}2,” Inorg. Chem. 1997, 36, 5962.

R. Gregory Peters, Byron L. Bennett, and Dean M. Roddick, "Thermal Elimination Reactions of (dfepe)Pt(CF3)X (Fluoroalkyl)phosphine Complexes (X = Cl, O2CCF3): Synthesis and Structural Characterization of an Unusual Chelate-Bridged Platinum(0) Complex, [(dfepe)Pt(CO)]2(m-dfepe)", Inorg. Chim. Acta. 1997, 265, 205.

R. C. Schnabel and D. M. Roddick, "New Electrophilic Iridium(I) Complexes: H-H and C-H Bond Heterolysis by [(dfepe)Ir(µ-X)]2 (X = O2CCF3, OTf)," Organometallics, 1996, 15, 3550.

B. L. Bennett and D. M. Roddick, "Synthesis and Structure of [(dfepe)Pt(µ-H)]2. An Unusual Example of Conformational Polymorphism," Inorg. Chem., 1996, 35, 4703.

R. C. Schnabel, P. S. Carroll and D. M. Roddick, "Polyhydride (Fluoroalkyl)phosphine Complexes of Iridium. Synthesis, Dynamics, and Reactivity Properties of (dfepe)2Ir2(µ-H)3(H)," Organometallics, 1996, 15, 655.

B. L. Bennet, J. Birnbaum, D. M. Roddick, "Protonation Studies of Electrophilic Platinum(II) Alkyl Complexes: Synthesis and Characterization of (dfepe)Pt(Me)X (X = O2CCF3, OSO2CF3, OSO3H)," Polyhedron, 1995, 14, 187.

R. K. Merwin and D. M. Roddick, " Synthesis and Characterization of Bifunctional trans-(Ph3P)2Pt(CO2Me)(X) Complexes," J. Organomet Chem. 1995, 487, 69.

D. M. Roddick and R. C. Schnabel, "(Fluoroalkyl)phosphine Coordination Chemistry," ACS Symp. Ser. 1994, 555, 421.

R. C. Schnabel and D. M. Roddick, "(Fluoroalkyl)phosphine Complexes of Rhodium and Iridium. Synthesis and Reactivity Properties of [(dfepe)Ir(µ-Cl)]2" Inorg. Chem. 1993, 32, 1513.

R. C. Schnabel and D. M. Roddick, "(Fluoroalkyl)phosphine Hydride Complexes of Iridium. Synthesis and Structure of (dfepe)2IrH and (dfepe)2Ir2(H)(µ-H)2(µ-O3SCF3)," Organometallics 1993, 12, 704.

M. S. Esslinger, J. D. Koola, A. C. Ontko, R. K. Merwin, and D. M. Roddick, "Synthesis, Structure and Reactivity Properties of (η5-C5H5)Ru[(C2F5)2P-CH2CH2P(C2F5)2]X Complexes: New Electrophilic Analogues to (η5-C5H5)Ru(CO)2X Systems," Organometallics 1992, 11, 3417.

R. K. Merwin, R. C. Schnabel, J. D. Koola, and D. M. Roddick, "Kinetics and Mechanism of Biaryl Reductive Elimination from Electron-Poor [(C6F5)2PCH2CH2P(C6F5)2]Pt(Ar)2 Complexes," Organometallics 1992, 11, 2972.

J. D. Koola and D. M. Roddick, "Activation of Hydrocarbons by a Ruthenium(II) (Fluoroalkyl)-phosphine Hydride Complex,"  J. Am. Chem. Soc. 1991, 113, 1450.

 J. D. Koola and D. M. Roddick, "Synthesis and Molecular Structure of a Difluorocarbene Complex, [(η5-C5Me5)Mo(CO)3(CF2)]OSO2CF3," Organometallics 1991, 10, 591.

M. F. Ernst and D. M. Roddick, "Chelate Binding Preferences in CpML4 Complexes: Preparation and Structure of trans-(η5-C5H5)Mo[(C6F5)2PCH2CH2P(C6F5)2](CO)Cl,"  Inorg. Chem. 1990, 29, 3627.

M. F. Ernst and D. M. Roddick, "Fluoroalkylphosphine Chemistry of Molybdenum. Synthesis, Structure, and Reactivity of (η6-C6H5Me)Mo[(C2F5)2PCH2CH2P(C2F5)2](N2)," Organometallics 1990, 9, 1586.

M. F. Ernst and D. M. Roddick, "Synthesis and Coordination Properties of Bis(bis(penta-fluoroethyl)phosphino)ethane," Inorg. Chem. 1989, 28, 1624.